Education
1993: The Bronx High School of Science, Bronx, New York

1997: Bachelor of Science, Department of Chemistry and Deparment of Engineering and Applied Science, California Institute of Technology, Pasadena, California

1999: Master of Science, Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts

2003: Doctorate of Philosophy, Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts

E-mail
wpk [at] ugcs [dot] caltech [dot] edu

Publications


My Doctoral Research

I was a graduate student in professor Bettina Voelker's group and worked on using Fenton-like chemistry to remediate groundwater.

A brief overview of Fenton chemistry . . .

In 1894, H. J. H. Fenton reported the oxidation of malic acid in a solution of ferrous ion and hydrogen peroxide. Further studies showed that the combination of Fe2+ and H2O2 can oxidize many substrates, and this type of chemistry is known as "Fenton chemistry."

It is generally believed that the Fenton reaction proceeds via this pathway:

Fe2+ + H2O2 ---> Fe3+ + OH- + OH*

where OH* denotes the hydroxyl radical. This reaction has a rate constant of 76 M-1 s-1 at pH 3, room temperature.
The iron is a catalyst in this system because it can be regenerated by

Fe3+ + H2O2 --> Fe2+ + HO2/O2- + H+

Fe3+ + HO2/O2- --> Fe2+ + O2 + H+

Some other important reactions involve the reactive radicals, OH* and HO2/O2-.

OH* + H2O2 --> HO2/O2- + H2O

OH* + Fe2+ --> Fe3+ + OH-

HO2/O2- + Fe2+ + H+ --> Fe3+ + H2O2

The system is not simple, and the nature of some of the intermediates are still being debated in literature.

The abstract of my doctoral work.


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