Education
1993: The Bronx High School of
Science, Bronx, New York
1997: Bachelor of Science, Department of Chemistry
and Deparment of Engineering and Applied
Science, California Institute of
Technology, Pasadena, California
1999: Master of Science, Department of Civil and Environmental
Engineering, Massachusetts Institute of
Technology, Cambridge, Massachusetts
2003: Doctorate of Philosophy, Department of Civil and Environmental
Engineering, Massachusetts Institute of
Technology, Cambridge, Massachusetts
E-mail
wpk [at] ugcs [dot] caltech [dot] edu
Publications
- Kwan, Wai P. and Voelker, Bettina M., "Predicting oxidation rates of
dissolved contaminants during in situ remediation using Fenton's
reaction." Abstracts of Papers of the American Chemical Society,
2004, 228, 352-ENVR.
- Kwan, Wai P. and Voelker, Bettina M. "Influence of electrostatics on
the oxidation rates of organic compounds in heterogeneous Fenton systems."
Environmental Science & Technology, 2004, 38(12), 3452-3431.
- Kwan, Wai P. and Voelker, Bettina M. "Rates of hydroxyl radical
generation and organic compound oxidation in mineral-catalyzed Fenton-like
systems." Environmental Science & Technology, 2003, 37(6),
1150-1158.
- Kwan, Wai P. and Voelker, Bettina M., "Decomposition of hydrogen
peroxide and organic compounds in the presence of dissolved iron and
ferrihydrite." Environmental Science & Technology, 2002,
36(7), 1467-1476.
- Kwan, Wai P. and Voelker, Bettina M., "Heterogeneous Fenton-like chain
reactions initiated by iron oxides." Abstracts of Papers of the
American Chemical Society, 2000, 220, 283-ENVR.

My Doctoral Research
I was a graduate student in professor Bettina
Voelker's group and worked on using Fenton-like chemistry to remediate
groundwater.
A brief overview of Fenton chemistry . . .
In 1894, H. J. H. Fenton reported the oxidation of malic acid in a
solution of ferrous ion and hydrogen peroxide. Further studies showed that
the combination of Fe2+ and H2O2 can
oxidize many substrates, and this type of chemistry is known as "Fenton
chemistry."
It is generally believed that the Fenton reaction proceeds via this
pathway:
Fe2+ + H2O2 ---> Fe3+
+ OH- + OH*
where OH* denotes the hydroxyl radical. This reaction has a
rate constant of 76 M-1 s-1 at pH 3, room
temperature.
The iron is a catalyst in this system because it can be regenerated by
Fe3+ + H2O2 --> Fe2+ +
HO2/O2- + H+
Fe3+ + HO2/O2- -->
Fe2+ + O2 + H+
Some other important reactions involve the reactive radicals,
OH* and HO2/O2-.
OH* + H2O2 -->
HO2/O2- + H2O
OH* + Fe2+ --> Fe3+ +
OH-
HO2/O2- + Fe2+
+ H+ --> Fe3+ +
H2O2
The system is not simple, and the nature of some of the intermediates are
still being debated in literature.
The abstract of my
doctoral work.
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